全文获取类型
收费全文 | 7653篇 |
免费 | 1971篇 |
国内免费 | 2828篇 |
专业分类
测绘学 | 310篇 |
大气科学 | 604篇 |
地球物理 | 3030篇 |
地质学 | 6048篇 |
海洋学 | 1313篇 |
天文学 | 140篇 |
综合类 | 374篇 |
自然地理 | 633篇 |
出版年
2024年 | 9篇 |
2023年 | 105篇 |
2022年 | 213篇 |
2021年 | 264篇 |
2020年 | 351篇 |
2019年 | 398篇 |
2018年 | 360篇 |
2017年 | 415篇 |
2016年 | 413篇 |
2015年 | 451篇 |
2014年 | 578篇 |
2013年 | 603篇 |
2012年 | 505篇 |
2011年 | 647篇 |
2010年 | 502篇 |
2009年 | 602篇 |
2008年 | 604篇 |
2007年 | 655篇 |
2006年 | 679篇 |
2005年 | 499篇 |
2004年 | 451篇 |
2003年 | 424篇 |
2002年 | 339篇 |
2001年 | 328篇 |
2000年 | 314篇 |
1999年 | 258篇 |
1998年 | 241篇 |
1997年 | 202篇 |
1996年 | 182篇 |
1995年 | 187篇 |
1994年 | 166篇 |
1993年 | 125篇 |
1992年 | 95篇 |
1991年 | 63篇 |
1990年 | 45篇 |
1989年 | 33篇 |
1988年 | 36篇 |
1987年 | 20篇 |
1986年 | 20篇 |
1985年 | 12篇 |
1984年 | 17篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1954年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
91.
运用80 t大型三维多功能土工试验机(3DMAS),进行了不同应力幅值比下粗粒土与结构接触面大型三维循环直剪试验,深入分析了应力控制往返椭圆剪切路径下接触面切向位移、非共轴角和剪切柔度等三维力学特性以及应力幅值比的影响规律。应力控制往返椭圆剪切路径下,接触面产生了明显的x向和y向位移、非共轴角和剪切柔度。x向和y向位移幅值、剪切柔度峰值均随循环剪切的进行逐渐减小而后趋于稳定,表现出演化特性。非共轴角受切向应力幅值及切向应力增量方向共同影响,其最值、稳定值随循环周次基本保持不变;正向剪切时非共轴角最大值(最小值)与反向剪切时最小值(最大值)基本出现在同一位置。接触面剪切柔度与非共轴角随旋转角度的变化趋势相反,剪切柔度的增加会抑制非共轴角的发展,反之亦然,两者对立统一。应力幅值比对接触面切向位移间椭圆关系及其时程变化形式、切向应力位移类椭圆关系等影响较小,主要影响切向位移幅值及其偏移程度、切向位移间椭圆关系的长短轴大小及方向、切向应力位移类椭圆关系的长短轴大小、非共轴角的数值及其随旋转角度的变化形式和最值出现位置、剪切柔度随旋转角度的变化形式和峰值及其产生位置等。应力幅值比越大,切向位移幅值越大、向负向偏移越大,剪切柔度峰值越大,随循环剪切的进行减小的速率越慢。应力幅值比ξτ=1和ξτ≠1时接触面非共轴角和剪切柔度随旋转角度的发展变化形式差别很大。 相似文献
92.
为研究应变速率对原状膨胀土力学性状的影响,通过GDS三轴试验系统进行了不同速率和围压下的固结不排水三轴剪切试验,分析了应力−应变曲线、孔隙水压力、剪切强度以及破坏模式随应变速率的变化规律。结果表明:不同应变速率下,膨胀土应力−应变曲线均呈应变硬化型。随着应变速率的增加,不排水剪切强度单调递增,引入应变速率参数ρ0.9后发现,不排水强度增长率为14.3%~23.2%,平均值为18.4%。低围压下,应变速率对孔隙水压力影响较小,随着围压的增大,孔隙水压力的发展趋势由软化型转变为硬化型,孔隙水压力峰值随应变速率的增大而减小。原状膨胀土应变速率效应与其多裂隙性密切相关,破坏形式表现为小应变速率下主剪切带与次剪切带共存,大应变速率下仅有主剪切带,裂隙或多剪切带的出现强化了膨胀土强度的应变速率效应。 相似文献
93.
《地学前缘(英文版)》2022,13(4):101379
The large tonnage Maoling gold deposit (25 t @ 3.2 g/t) is located in the southwest Liaodong Peninsula, North China Craton. The deposit is hosted in the Paleoproterozoic metamorphic rocks. Four stages of mineralization were identified in the deposit: (stage I) quartz-arsenopyrite ± pyrite, (stage II) quartz-gold- arsenopyrite-pyrrhotite, (stage III) quartz-gold- polymetallic sulfide, and (stage IV) quartz-calcite-pyrrhotite. In this paper, we present fluid inclusion, C-H-O-S-Pb-He-Ar isotope data, zircon U-Pb, and gold-bearing sulfide (i.e. arsenopyrite and pyrrhotite) Rb-Sr age of the Maoling gold deposit to constrain its genesis and ore-forming mechanism. Three types of fluid inclusions were distinguished in quartz-bearing veins, including liquid-rich two-phase (WL type), gas-rich two-phase (GL type), and daughter mineral-bearing fluid inclusions (S type). Fluid inclusions data show that the homogenization at temperatures 197 to 372 °C for stage I, 126 to 319 °C for stage II, 119 to 189 °C for stage III, and 115 to 183 °C for stage IV, with corresponding salinities of 3.7 to 22.6 wt.%, 4.7 to 23.2 wt.%, 5.3 to 23.2 wt.%, and 1.7 to 14.9 wt.% NaCl equiv., respectively. Fluid boiling was the critical factor controlling the gold and associated sulfide precipitation at Maoling. Hydrogen and oxygen stable isotopic analyses for quartz yielded δ18O = ?5.0‰ to 9.8‰ and δ D = ?133.5‰ to ?77.0‰. Carbon stable isotopic analyses for calcite and ankerite yielded δ13C = ?2.3‰ to ?1.2‰ and O = 7.9‰ to 14.1‰. The C-H-O isotope data show that the ore-forming fluids were originated from magmatic water with meteoric water input during mineralization. Hydrothermal inclusions in arsenopyrite have 3He/4He ratios of 0.002 Ra to 0.054 Ra, and 40Ar/36Ar rations of 1225 to 3930, indicating that the ore-forming fluids were dominantly derived from crustal sources almost no mantle input. Sulfur isotopic values of Maoling fine-grained granite range from 6.‰1 to 9.8‰, with a mean of 7.7‰, δ34S values of arsenopyrite from the mineralized phyllite (host rock) range from 8.9‰ to 10.6‰, with a mean of 10.0‰, by contrast, δ34S values of sulfides from ore vary between 4.3‰ and 10.6‰, with a mean of 6.8‰, suggesting that sulfur was mainly originated from both the host rock and magma. Lead radioactive isotopic analyses for sulfides yielded 206Pb/204Pb = 15.830–17.103, 207Pb/204Pb = 13.397–15.548, 208Pb/204Pb = 35.478–36.683, and for Maoling fine-grained granite yielded 206Pb/204Pb = 18.757–19.053, 207Pb/204Pb = 15.596–15.612, and 208Pb/204Pb = 38.184–39.309, also suggesting that the ore-forming materials were mainly originated from the host rocks and magma. Zircon U-Pb dating demonstrates that the Maoling fine-grained granite was emplaced at 192.7 ± 1.8 Ma, and the host rock (mineralized phyllite) was emplaced at some time after 2065.0 ± 27.0 Ma. Arsenopyrite and pyrrhotite give Rb–Sr isochron age of 188.7 ± 4.5 Ma, indicating that both magmatism and mineralization occurred during the Early Jurassic. Geochronological and geochemical data, together with the regional geological history, indicate that Early Jurassic magmatism and mineralization of the Maoling gold deposit occurred during the subducting Paleo-Pacific Plate beneath Eurasia, and the Maoling gold deposit is of the intrusion-related gold deposit type. 相似文献
94.
Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry 下载免费PDF全文
Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water. 相似文献
95.
Experimental and numerical investigation of groundwater head losses on and nearby short intersections between disc-shaped fractures 下载免费PDF全文
Discrete fracture models are used for investigating precise processes of groundwater flow in fractured rocks,while a disc-shaped parallel-plates model for a single fracture is more reasonable and efficient for computational treatments.The flow velocity has a large spatial differentiation which is more likely to produce non-linear flow and additional head losses on and nearby intersections in such shaped fractures,therefore it is necessary to understand and quantify them.In this study,both laboratory experiments and numerical simulations were performed to investigate the total head loss on and nearby the intersections as well as the local head loss exactly on the intersections,which were not usually paid sufficient attention or even ignored.The investigation results show that these two losses account for 29.17%-84.97%and 0-73.57%of the entire total head loss in a fracture,respectively.As a result,they should be necessarily considered for groundwater modeling in fractured rocks.Furthermore,both head losses become larger when aperture and flow rate increase and intersection length decreases.Particularly,the ratios of these two head losses to the entire total head loss in a fracture could be well statistically explained by power regression equations with variables of aperture,intersection length,and flow rates,both of which achieved high coefficients of determination.It could be feasible through this type of study to provide a way on how to adjust the groundwater head from those obtained by numerical simulations based on the traditional linear flow model.Finally,it is practicable and effective to implement the investigation approach combining laboratory experiments with numerical simulations for quantifying the head losses on and nearby the intersections between disc-shaped fractures. 相似文献
96.
在围压(外压)或孔压(内压)发生变化的条件下,致密砂岩及泥页岩泊松比的变化特征及机制仍有待厘清。本研究从Terzaghi有效应力理论和国内学者提出的新有效应力概念出发,基于松辽盆地高台子组致密砂岩、青山口组泥页岩三向动、静态泊松比测定结果,剖析了两类岩石泊松比的变化特征及机制。岩石样品三向泊松比变化曲线的分布呈现显著的各向异性,这将对压裂缝的延展规律产生一定的影响;就“有效应力”概念厘定的科学性而言,“Terzaghi有效应力”适用于裂缝较为发育的储层,而“新有效应力”适用于孔隙度较大且分布较为均匀的泥页岩。结论将为致密油气的有效开发提供较为重要的理论依据。 相似文献
97.
塔城盆地地下水氟分布特征及富集机理 总被引:2,自引:0,他引:2
塔城盆地位于新疆维吾尔自治区西北部,干旱少雨,蒸发强烈。但相对于新疆其他盆地,塔城盆地地下水水质相对较好,溶解性总固体和F-含量相对较低。为解译这种差异及盆地内高氟地下水的成因,本文在对盆地地下水样品水化学组分系统分析的基础上,结合多种水文地质调查数据,利用数理统计、离子比及主成分分析等手段,研究高氟水的成因及其分布规律。结果表明:受气候以及地质等因素控制,研究区地下水氟浓度总体较低,高氟水主要分布于扇前洼地及盆地中部的低洼地带;受承压含水层的顶托补给,地下水氟浓度呈现出上高下低的垂向分带特征。研究区地下水径流途径短,水循环快,水岩相互作用时间较短,且山区地下水以深径流形式循环补给平原区深层承压含水层,再顶托补给潜水,避免了强烈的蒸发浓缩作用。山前洪积扇地下水氟富集主要受控于沉积地层中含氟矿物的风化溶解,而岩石风化、蒸发浓缩、阳离子交换、竞争吸附为平原区地下水氟浓度的主要影响因素。 相似文献
98.
应用气相色谱-气体同位素质谱(GC-C-IRMS)分析正构烷烃单体碳同位素之前,需要对饱和烃样品中正构烷烃和异构烷烃进行预分离、富集,在预分离和富集过程中正构烷烃单体碳同位素是否发生分馏是高精度分析正构烷烃单体碳同位素比值(δ~(13)C)的关键。本文以正构烷烃混合溶液为对象,利用柱色谱、5■分子筛络合、环己烷-正戊烷混合溶剂两次洗脱,GC-C-IRMS分析正构烷烃单体碳同位素,研究前处理过程中正构烷烃单体碳同位素是否发生分馏。结果表明:使用柱色谱分离前后,多数正构烷烃单体碳同位素比值相差-0.2‰~0.2‰;当5■分子筛不完全络合时,未络合的正构烷烃单体碳同位素比值偏重约0.7‰,可能发生了微弱的碳同位素分馏,但并未影响洗脱后的正构烷烃单体碳同位素比值;使用环己烷-正戊烷混合溶剂洗脱前后,碳同位素比值相差-0.2‰~0.5‰,以同样方式洗脱第二次,获得的正构烷烃单体碳同位素比值与模拟样品相差-0.3‰~0.2‰。分析不同回收率(20%)正构烷烃的单体碳同位素比值,处理前后的差值基本在0.3‰以内,可见当正构烷烃回收率低至20%左右时,其单体碳同位素仍未发生明显分馏。柱色谱分离-5■分子筛络合-混合溶剂洗脱方法适用于回收率大于20%的正构烷烃单体碳同位素分析。 相似文献
99.
碳酸盐岩风化作用(即岩溶作用)能够吸收大气二氧化碳(CO_2),形成溶解无机碳(DIC,dissolved inorganic carbon),被认为是一种重要的陆地碳汇,其在全球碳收支平衡和未来陆地增汇中可能会有重要贡献。然而,目前对岩溶碳汇的稳定性还存在争议,一些学者认为岩溶地下水出露地表后会发生CO_2脱气,对岩溶碳汇通量估算带来不确定性。本文以广西桂林长流水表层岩溶泉补给的溪流(约2.7km长)为例,利用水化学和同位素质谱仪测试技术,研究了溪水水化学指标和溶解无机碳同位素(δ~(13)C_(DIC))沿流程变化,探讨了溪流CO_2脱气过程、通量及其影响因素,以更好地了解岩溶碳汇的稳定性。结果表明:从泉口向下游,在陡坡地段(C1~C14段,长约270m,坡度约10°),溪水pH值、方解石饱和指数和δ~(13)C_(DIC)沿流程分别升高了0.9、0.9和1.8‰,而CO_2分压、电导率、Ca~(2+)浓度和DIC浓度分别下降了85%、34μS/cm、0.2mmol/L和0.7mmol/L,说明溪水发生了显著的CO_2脱气,并伴随碳酸钙沉淀。而在平缓地段(C18~C26段,长约2.1km,坡度1°),溪水各水化学指标和δ~(13)C_(DIC)变化较小,指示CO_2脱气作用较弱。这些发现表明溪流CO_2脱气受到了地形决定的水动力条件控制。另外,在下游渠段,受支流汇入影响,溪水pH值和方解石饱和指数有所降低,在一定程度上抑制了CO_2脱气。溪流CO_2脱气能够抵消部分岩溶作用固定的大气CO_2量,但是在长流水这一高地势、低流量且有碳酸钙沉积的环境下,其抵消的量也仅占29%。对于在低缓地区受流量很大的岩溶泉/地下河补给的河流,其CO_2脱气作用对岩溶碳汇的影响有限,加之受可能增强的水生光合生物固碳效应影响,岩溶碳汇应具有很高的稳定性。 相似文献
100.